Distorted phthalocyanines by click chemistry: Photoacoustic, photothermal, and surface-enhanced resonance Raman studies Journal Article


Authors: Rizvi, W.; Berisha, N.; Farley, C.; Bhupathiraju, N. V. S. D. K.; Andreou, C.; Khwaja, E.; Fuentes, G. V.; Kircher, M. F.; Gao, R.; Drain, C. M.
Article Title: Distorted phthalocyanines by click chemistry: Photoacoustic, photothermal, and surface-enhanced resonance Raman studies
Abstract: Distortion of nominally planar phthalocyanine macrocycles affects the excited state dynamics in that most of the excited-state energy decays through internal conversion. A click-type annulation reaction on a perfluorophthalocyanine platform appending a seven-membered ring to the β-positions on one or more of the isoindoles distorts the macrocycle and modulates solubility. The distorted derivative enables photoacoustic imaging, photothermal effects, and strong surface-enhanced resonance Raman signals. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Keywords: synthesis (chemical); click chemistry; excited states; raman spectroscopy; photothermal therapy; phthalocyanines; photo-acoustic imaging; photoacoustic imaging; photoacoustic effect; photoacoustic spectroscopy; excited-state dynamics; photothermal effects; seven-membered rings; surface enhanced resonance
Journal Title: Chemistry - A European Journal
Volume: 25
Issue: 64
ISSN: 0947-6539
Publisher: Wiley V C H Verlag Gmbh  
Date Published: 2019-11-18
Start Page: 14517
End Page: 14521
Language: English
DOI: 10.1002/chem.201903463
PUBMED: 31515825
PROVIDER: scopus
PMCID: PMC6861660
DOI/URL:
Notes: Article -- Export Date: 2 December 2019 -- Source: Scopus
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  1. Moritz Florian Kircher
    55 Kircher
  2. Chrysafis   Andreou
    22 Andreou
  3. Naxhije Berisha
    11 Berisha