Authors: | Rizvi, W.; Berisha, N.; Farley, C.; Bhupathiraju, N. V. S. D. K.; Andreou, C.; Khwaja, E.; Fuentes, G. V.; Kircher, M. F.; Gao, R.; Drain, C. M. |
Article Title: | Distorted phthalocyanines by click chemistry: Photoacoustic, photothermal, and surface-enhanced resonance Raman studies |
Abstract: | Distortion of nominally planar phthalocyanine macrocycles affects the excited state dynamics in that most of the excited-state energy decays through internal conversion. A click-type annulation reaction on a perfluorophthalocyanine platform appending a seven-membered ring to the β-positions on one or more of the isoindoles distorts the macrocycle and modulates solubility. The distorted derivative enables photoacoustic imaging, photothermal effects, and strong surface-enhanced resonance Raman signals. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
Keywords: | synthesis (chemical); click chemistry; excited states; raman spectroscopy; photothermal therapy; phthalocyanines; photo-acoustic imaging; photoacoustic imaging; photoacoustic effect; photoacoustic spectroscopy; excited-state dynamics; photothermal effects; seven-membered rings; surface enhanced resonance |
Journal Title: | Chemistry - A European Journal |
Volume: | 25 |
Issue: | 64 |
ISSN: | 0947-6539 |
Publisher: | Wiley V C H Verlag Gmbh |
Date Published: | 2019-11-18 |
Start Page: | 14517 |
End Page: | 14521 |
Language: | English |
DOI: | 10.1002/chem.201903463 |
PUBMED: | 31515825 |
PROVIDER: | scopus |
PMCID: | PMC6861660 |
DOI/URL: | |
Notes: | Article -- Export Date: 2 December 2019 -- Source: Scopus |