The synthesis of a key intermediate en route to gelsemine: A program based on intramolecular displacement of the carbon-oxygen bond of a strategic oxetane Journal Article

  


Authors: Ng, F. W.; Lin, H.; Tan, Q.; Danishefsky, S. J.
Article Title: The synthesis of a key intermediate en route to gelsemine: A program based on intramolecular displacement of the carbon-oxygen bond of a strategic oxetane
Abstract: The synthesis of key intermediate 30 en route to gelsemine has been accomplished from known aldehyde 10 via oxetane 19 featuring stereospecific Claisen rearrangement and Lewis acid-catalyzed oxetane ring opening. © 2002 Published by Elsevier Science Ltd.
Keywords: unclassified drug; oxygen; chemical structure; catalysis; stereospecificity; synthesis; chemical bond; organic chemistry; carbon; alkaloid; gelsemine; article; oxetane derivative
Journal Title: Tetrahedron Letters
Volume: 43
Issue: 4
ISSN: 0040-4039
Publisher: Pergamon-Elsevier Science Ltd  
Date Published: 2002-01-21
Start Page: 545
End Page: 548
Language: English
DOI: 10.1016/s0040-4039(01)02212-2
PROVIDER: scopus
DOI/URL:

http://www.scopus.com/inward/record.url?eid=2-s2.0-0037147968&partnerID=40&md5=a38b9af2aacafcdd9a1ab11a6325bf76
Notes: Export Date: 14 November 2014 -- Source: Scopus
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MSK Authors
  1. Hong Lin
    10 Lin
  2. Qiang Tan
    3 Tan
  3. Samuel J Danishefsky
    539 Danishefsky
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