Authors: | Dai, M.; Danishefsky, S. J. |
Article Title: | An oxidative dearomatization cyclization model for cortistatin A |
Abstract: | The feasibility of a hypervalent iodine-mediated oxidative dearomatization/cyclization to produce the oxabicyclo[3.2.1]octene of cortistatin A has been demonstrated through a model study. An interesting tandem cyclization via a Ritter intermediate has been observed when a slightly different substrate was used. © 2009 The Japan Institute of Heterocyclic Chemistry All rights reserved. |
Keywords: | cortistatin; cyclization; hypervalent iodine; natural product; oxidative dearomatization |
Journal Title: | Heterocycles |
Volume: | 77 |
Issue: | 1 |
ISSN: | 0385-5414 |
Publisher: | Pergamon-Elsevier Science Ltd |
Date Published: | 2009-01-01 |
Start Page: | 157 |
End Page: | 161 |
Language: | English |
DOI: | 10.3987/com-08-s(f)6 |
PROVIDER: | scopus |
DOI/URL: | |
Notes: | --- - "Cited By (since 1996): 14" - "Export Date: 30 November 2010" - "CODEN: HTCYA" - "Source: Scopus" |