Authors: | Mandal, M.; Danishefsky, S. J. |
Article Title: | Probing the formation and chemistry of enoxyoxirane derivatives in the C-ring en route to guanacastepene |
Abstract: | Enol acetate and silyl enol ether, derivatives of 2 and 3 undergo stereoselective epoxidation from the β-face of the C13-C14 olefin. The progression of these compounds to the C13 acetoxy C14 ketones is described. © 2004 Published by Elsevier Ltd. |
Keywords: | chemical structure; molecular probe; synthesis; stereochemistry; silane derivative; ketone derivative; epoxidation; alkene derivative; article; ethylene oxide derivative |
Journal Title: | Tetrahedron Letters |
Volume: | 45 |
Issue: | 19 |
ISSN: | 0040-4039 |
Publisher: | Pergamon-Elsevier Science Ltd |
Date Published: | 2004-05-03 |
Start Page: | 3831 |
End Page: | 3833 |
Language: | English |
DOI: | 10.1016/j.tetlet.2004.02.162 |
PROVIDER: | scopus |
DOI/URL: | |
Notes: | Tetrahedron Lett. -- Cited By (since 1996):15 -- Export Date: 16 June 2014 -- CODEN: TELEA -- Source: Scopus |