Application of an intramolecular dipolar cycloaddition to an asymmetric synthesis of the fully oxygenated tricyclic core of the stemofoline alkaloids Journal Article

   

Authors:	Carra, R. J.; Epperson, M. T.; Gin, D. Y.
Article Title:	Application of an intramolecular dipolar cycloaddition to an asymmetric synthesis of the fully oxygenated tricyclic core of the stemofoline alkaloids
Abstract:	An intramolecular non-stabilized azomethine ylide dipolar cycloaddition was applied toward the first non-racemic synthesis of the fully oxygenated bridged pyrrolizidine core (45) of (+)-stemofoline (1) in 11 steps from a commercially available starting material. © 2008 Elsevier Ltd. All rights reserved.
Keywords:	unclassified drug; drug structure; nuclear magnetic resonance spectroscopy; stereochemistry; cycloaddition; asymmetric synthesis; alkaloid derivative; pyrrolizidine alkaloid; stemofiline; hydrogenolysis
Journal Title:	Tetrahedron
Volume:	64
Issue:	17
ISSN:	0040-4020
Publisher:	Elsevier Inc.
Date Published:	2008-04-21
Start Page:	3629
End Page:	3641
Language:	English
DOI:	10.1016/j.tet.2008.02.008
PROVIDER:	scopus
PMCID:	PMC2352155
PUBMED:	18443655
DOI/URL:	http://www.scopus.com/inward/record.url?eid=2-s2.0-40649088525&partnerID=40&md5=815568c1f2316099e05ac1b8f47d1229
Notes:	--- - "Cited By (since 1996): 8" - "Export Date: 17 November 2011" - "CODEN: TETRA" - "Source: Scopus"

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