Synthetic access to the chlorocyclopentane cores of the proposed original and revised structures of palau'amine Journal Article
| Authors: | Bultman, M. S.; Ma, J.; Gin, D. Y. |
| Article Title: | Synthetic access to the chlorocyclopentane cores of the proposed original and revised structures of palau'amine |
| Abstract: | (Chemical Equation Presented) Core knowledge: The synthesis of the functionalized cores of both the originally proposed and revised structures of palau'amine have been achieved (see structures). A Diels-Alder/[3,3]-sigmatropic rearrangement sequence and a Beckmann rearrangement enable the stereo-controlled formation of the highly congested cores. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. |
| Keywords: | chemistry; amines; chemical structure; molecular structure; amination; chemical reactions; alkaloids; diels-alder reaction; synthesis; total synthesis; synthesis (chemical); stereoisomerism; spiro compound; spiro compounds; organic compounds; sigmatropic rearrangement; chlorine; cyclopentane derivative; guanidine derivative; palau'amine; cyclopentanes; guanidines |
| Journal Title: | Angewandte Chemie - International Edition |
| Volume: | 47 |
| Issue: | 36 |
| ISSN: | 1433-7851 |
| Publisher: | Wiley Blackwell |
| Date Published: | 2008-08-25 |
| Start Page: | 6821 |
| End Page: | 6824 |
| Language: | English |
| DOI: | 10.1002/anie.200801969 |
| PUBMED: | 18655078 |
| PROVIDER: | scopus |
| PMCID: | PMC2610474 |
| DOI/URL: | |
| Notes: | --- - "Cited By (since 1996): 18" - "Export Date: 17 November 2011" - "CODEN: ACIEA" - "Source: Scopus" |
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