Solid support oligosaccharide synthesis: Construction of β-linked oligosaccharides by coupling of glycal derived thioethyl glycosyl donors Journal Article
| Authors: | Zheng, C.; Seeberger, P. H.; Danishefsky, S. J. |
| Article Title: | Solid support oligosaccharide synthesis: Construction of β-linked oligosaccharides by coupling of glycal derived thioethyl glycosyl donors |
| Abstract: | A solution to the problem of a solid-phase synthesis of β-(1-4) linked glucosides is described. The method involves conversion of polymer bound glycal to polymer bound thioethyl glucosyl donor bearing an a-oriented pivaloxy group at C2. The latter directs couplings with solution-based glycal acceptors in the β-sense. The ready-reiteratability of the method was demonstrated. |
| Journal Title: | Journal of Organic Chemistry |
| Volume: | 63 |
| Issue: | 4 |
| ISSN: | 0022-3263 |
| Publisher: | American Chemical Society |
| Date Published: | 1998-02-20 |
| Start Page: | 1126 |
| End Page: | 1130 |
| Language: | English |
| PROVIDER: | scopus |
| DOI: | 10.1021/jo971606h |
| DOI/URL: | |
| Notes: | Article -- Export Date: 12 December 2016 -- Source: Scopus |
