A remarkable pyranose to furanose isomerization mediated by an "anomeric" silyloxy function Journal Article


Authors: Bhattacharya, S. K.; Chen, X. T.; Gutteridge, C. E.; Danishefsky, S. J.
Article Title: A remarkable pyranose to furanose isomerization mediated by an "anomeric" silyloxy function
Abstract: The conversion of 3 to 6 is accomplished in high yields in three steps. The sequence greatly simplifies access to eleutherobin 1.
Keywords: unclassified drug; methylation; antineoplastic activity; drug synthesis; conformational transition; natural product; structure analysis; reaction analysis; furan derivative; isomerization; rearrangements; crystallography; isomerism; eleutherobin; nuclear overhauser effect; antitumor compounds; article; furanose; pyran derivative; pyranose
Journal Title: Tetrahedron Letters
Volume: 40
Issue: 17
ISSN: 0040-4039
Publisher: Pergamon-Elsevier Science Ltd  
Date Published: 1999-04-23
Start Page: 3313
End Page: 3316
Language: English
DOI: 10.1016/s0040-4039(99)00499-2
PROVIDER: scopus
DOI/URL:
Notes: Article -- Export Date: 16 August 2016 -- Source: Scopus
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