Thermal intermolecular hetero Diels-Alder cycloadditions of aldehydes and imines via o-quinone dimethides Journal Article
| Authors: | Hentemann, M. F.; Allen, J. C.; Danishefsky, S. J. |
| Article Title: | Thermal intermolecular hetero Diels-Alder cycloadditions of aldehydes and imines via o-quinone dimethides |
| Abstract: | Highly regio- and stereodefined products are obtained from the cycloaddition of benzocyclobutenes with aldehydes and imines (see scheme). These high-yielding thermal reactions can be performed in the absence of catalysis - even at ambient temperature. Y = H, OMe; X = NR', O; TBS = tert- butyldimethylsilyl. |
| Keywords: | quinone derivative; temperature; catalysis; reaction analysis; synthesis; stereochemistry; cycloadditions; synthetic methods; heterocycles; article; imine; aldehyde derivative; nitrogen heterocycles |
| Journal Title: | Angewandte Chemie - International Edition |
| Volume: | 39 |
| Issue: | 11 |
| ISSN: | 1433-7851 |
| Publisher: | Wiley Blackwell |
| Date Published: | 2000-06-01 |
| Start Page: | 1937 |
| End Page: | 1940 |
| Language: | English |
| DOI: | 10.1002/1521-3773(20000602)39:11<1937::aid-anie1937>3.0.co;2-e |
| PROVIDER: | scopus |
| PUBMED: | 10940987 |
| DOI/URL: | |
| Notes: | Export Date: 18 November 2015 -- Source: Scopus |
