Novel synthetic approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene skeleton Journal Article

  


Authors: Coltart, D.; Danishefsky, S. J.
Article Title: Novel synthetic approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene skeleton
Abstract: (Matrix presented) An efficient and highly stereocontrolled approach to the 8,10-dimethyl anti-syn-anti-perhydrophenanthrene carbon skeleton starting with the Wieland-Miescher ketone is described. The approach centers on a Diels-Alder-angular methylation-deoxygenation sequence.
Keywords: methylation; chemistry; magnetic resonance spectroscopy; nuclear magnetic resonance spectroscopy; oxygenation; diels alder reaction; oxidation reduction reaction; oxidation-reduction; synthesis; stereochemistry; stereoisomerism; ketone; ketones; ketone derivative; phenanthrene derivative; phenanthrenes; article
Journal Title: Organic Letters
Volume: 5
Issue: 8
ISSN: 1523-7060
Publisher: American Chemical Society  
Date Published: 2003-04-17
Start Page: 1289
End Page: 1292
Language: English
DOI: 10.1021/ol034213f
PUBMED: 12688741
PROVIDER: scopus
DOI/URL:

http://www.scopus.com/inward/record.url?eid=2-s2.0-0037925371&partnerID=40&md5=4138578d0983515f6cd1e226d0fbadbc
Notes: Export Date: 12 September 2014 -- Source: Scopus
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MSK Authors
  1. Don Coltart
    6 Coltart
  2. Samuel J Danishefsky
    539 Danishefsky
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