Authors: | Mandal, M.; Danishefsky, S. J. |
Article Title: | Probing competitive pathways in building a hydroazulene moiety by reductive cyclization |
Abstract: | Deuterium tracing and deuterium isotope effects demonstrate competitive pathways for the reduction of vinyl iodide in 3 (in the context of a proximal keto function) en route to guanacastepene. © 2004 Published by Elsevier Ltd. |
Keywords: | cyclization; oxidation; molecular probe; vinyl derivative; synthesis; stereochemistry; reduction; deuterium; iodine derivative; azulene derivative; article |
Journal Title: | Tetrahedron Letters |
Volume: | 45 |
Issue: | 19 |
ISSN: | 0040-4039 |
Publisher: | Pergamon-Elsevier Science Ltd |
Date Published: | 2004-05-03 |
Start Page: | 3827 |
End Page: | 3829 |
Language: | English |
DOI: | 10.1016/j.tetlet.2004.02.161 |
PROVIDER: | scopus |
DOI/URL: | |
Notes: | Tetrahedron Lett. -- Cited By (since 1996):9 -- Export Date: 16 June 2014 -- CODEN: TELEA -- Source: Scopus |