Intramolecular Diels-Alder reactions of cycloalkenones: Translation of high endo selectivity to trans junctions Journal Article
| Authors: | Ross, A. G.; Li, X.; Danishefsky, S. J. |
| Article Title: | Intramolecular Diels-Alder reactions of cycloalkenones: Translation of high endo selectivity to trans junctions |
| Abstract: | Intramolecular Diels-Alder reactions of cyclobutenone and larger cycloalkenones are described. High levels of endo addition attained from Lewis acid catalysis translate to trans hydrindene junctions upon fragmentation of the tricyclic adducts. © 2012 American Chemical Society. |
| Keywords: | unclassified drug; chemistry; chemical structure; catalysis; chemical reactions; lewis acid; diels alder reaction; synthesis (chemical); fragmentation reaction; cycloalkene; cyclobutenone; cyclobutane; cycloalkenones; intramolecular diels-alder reaction; lewis acid catalysis; cycloalkenone |
| Journal Title: | Journal of the American Chemical Society |
| Volume: | 134 |
| Issue: | 38 |
| ISSN: | 0002-7863 |
| Publisher: | American Chemical Society |
| Date Published: | 2012-09-26 |
| Start Page: | 16080 |
| End Page: | 16084 |
| Language: | English |
| DOI: | 10.1021/ja307708q |
| PROVIDER: | scopus |
| PMCID: | PMC3464979 |
| PUBMED: | 22950514 |
| DOI/URL: | |
| Notes: | --- - "Export Date: 2 November 2012" - "CODEN: JACSA" - "Source: Scopus" |
