Authors: | Liu, H.; Siegel, D. R.; Danishefsky, S. J. |
Article Title: | Studies directed toward the synthesis of terreulactone A: Rapid construction of the A, B, C rings |
Abstract: | An efficient, rapid synthesis of the A, B, C rings of terreulactone A is described. Key steps in the synthesis include a diastereoselective benzylic acid rearrangement to create the desired quaternary center at C2 and a mild bromolactonization to assemble the lactonic ring A. © 2006 American Chemical Society. |
Keywords: | chemistry; chemical structure; molecular structure; cyclization; aspergillus; synthesis; biological product; biological products; sesquiterpenes; sesquiterpene; terreulactone a |
Journal Title: | Organic Letters |
Volume: | 8 |
Issue: | 3 |
ISSN: | 1523-7060 |
Publisher: | American Chemical Society |
Date Published: | 2006-02-02 |
Start Page: | 423 |
End Page: | 425 |
Language: | English |
DOI: | 10.1021/ol052618p |
PUBMED: | 16435850 |
PROVIDER: | scopus |
DOI/URL: | |
Notes: | --- - "Cited By (since 1996): 16" - "Export Date: 4 June 2012" - "Source: Scopus" |